The chemistry of food lipids is complicated because they are diverse types of compounds that undergo many interactions with other components of a food. Many important and well-understood chemical changes that occur in an isolated lipid may be modified by such factors as location of the lipid in a tissue system, the presence or absence of water, and the imposition of such stresses as heat or radiation.  Metals, both in the free state as irons and as components of organ metallic compounds, affect the chemistry of lipids, especially in oxidation reactions. Non-lipid components of a food may interact with lipids and this can produce change in food quality.

                DEFINITION AND CLASSIFICATION OF LIPIDS

  The consumer and the processor of foods utilize substances from the nutrients group known as fats and oils. Fats and oils represent the most prevalent single category of a series of compounds known as lipids.The word "lipid" is defined in Webster’s unabridged dictionary as “any of a group substance that sparingly soluble in ether, chloroform, or other solvents for fats but are only sparingly soluble in water, that with proteins and carbohydrates constitute the and principal structural components of living cells, and related and derived compounds, and sometimes steroids and carotenoids, " This definition describes a broad  group of substances that have some properties in common and have some compositional similarities.   

  A classification of lipids proposed by Bloor contains the following elements, which are useful in distinguishing the many lipid substances:

  1.Simple lipids (neutral lipids)-esters of fatty acids with alcohols.

      a.  Fats: esters of fatty acids with glycerol.

      b.  Waxes; esters of fatty acids with alcohols other than glycerol.

  2.Compound lipids-compounds containing other groups in addition ester of a fatty acid with an alcohol.

     a.Phospholipids (phosphatides): esters containing fatty acids, phosphoric acid and other groups usually containing nitrogen.

     b.Cerebrosides (phosphatides); compounds containing fatty acids, a carbohydrate and a nitrogen moiety, but no phosphoric acid

     c.Other compound lipids: sphingolipids: sphingolipids and sulfolipids

  3.Derived lipids-substances derived from neutral lipids or compound lipids and having general properties of lipids.

   a.Fatty acids

   b.Alcohols: usually normal chain higher alcohols and sterols

   c.Hydrocarbons

  Foods may contain any or all of these substances but those of greatest concern are the fats or glycosides and the phosphatides. The term “fatis” applicable to all triglycerides regardless of whether they are normally nonliquid or liquid at ambient temperatures. Liquid fats are commonly referred to as oils. Such oils as soybean oil, cottonseed oil, and olive oil are of plant origin, lard and tallow are examples of nonliquid fats from animals, yet fat from the horse is liquid at ambient temperatures and is referred to as horse oil.

  Fats and oils also can be classed according to “group characteristics.” Five well-recognized groups are the milkfat group, the lauric acid group, the oleiclinoleic acid group, the linolenic acid group, and the animal depot-fats group.

  The milkfat group pertains essentially to the milk of ruminants and especially to that of the cow, although in certain areas milk of the water buffalo of sheep and goats may be prominent. , Milk fats are characterized by 30-40% oleic, 25-32% palmitic, and 10-15% stearic acids. They generally have substantial amounts of c4-c12 acids and are the only commonly used fats to contain butyric acid, which composition is particularly susceptible to variation as a consequence of the animal’s diet.

  The lauric acid group is characterized by a high proportion (40-50%)of lauric acid (c12) and lesser amounts of c8, c10, c14, c16, and c18 acids. the unsaturated acid content is very low and this contributes to extremely good shelf life. These fats generally melt at low temperatures because of the short carbon chains present. The most widely used fats of this group are from the coconut, seeds of the oil palm, and the babassu or the coquilla nut.

  The oleic-linole9oc acid group, the largest and most varied group, contains only fats and oils of vegetable origin. These fats usually contain less than 20% saturated fatty acids, with oleic and linoleic acids being dominant. Such fats are commonly derived from seeds of cotton, corn, sesame, peanut, sunflower, and safflower and the seed coat or fruit pulp of the olive and the oil palm.

  Fats of the linolenic acid group contain high levels oleic and linoleic acid. The most although they also may contain high levels of oleic and linoleic acid. The most important food oil of this group is that from the soybean. Other is wheat germ oil, hempseed oil. Perilla oil, and linseed oil. The high linolenic acid content contributes to the during oil characteristic, especially of linseed oil which contains up to 50% linolenic acid.

  The animal fat group consists mainly of lard from the pig and tallows from bovine and ovine sources; these are characterized by 30-40% c16 and C18-saturated fatty acids and up to 60% oleic and linoleic acids. The melting points of these fats are types of glycerides present, with respect to the latter point, seed fats with as much as 60%saturated fatty acids often contain negligible may contain up to 26%trisaturated glycerides. Differences in triglyceride composition affect physical properties, and this in turn greatly influences the use to which a given fat is put.

                        ROLE AND USE OF LIPIDS IN FOODS

     Fats and oils the most concentrated source or food energy. Provide 9 kcal of energy per gram, which is approximately, double the energy provided they contribute to food flavor and palatability as well as to the feeling satiety after eating.

  Lipids, cholesterol, and cholesterol esters are important to the structure, composition, and permeable membranes and cell walls. They perform a function of energy storage in seeds, fruits of plants and animals. Lipids are major component of adipose tissue internal organs, and as a contributor to body shape.

  Fats and oils are used as frying fats or cooling oils where their role is to provide a controlled heat-exchange medium as well as to contribute to color and flavor.As shortenings, they impart as: “short” or tender quality to baked goods through a combination of lubrication and an ability to alter interaction among other constituents.As salad oils, they contribute to mouth feel and as carrier for flavors, and when emulsified with other ingredients they perform the same functions in the form of viscous pour able dressing or semisolid fatty foods know as mayonnaise or salad dressing. Margarines are used both for baking and cooking and as table spreads. Specially selected or manufactured fats are useful in confections, especially as enrobing or coating agents. These fats must have a short melting rang at body temperature.

  Other fatty materials, such as the mono-and diglycerides, and certain phosphlipids, such as lecithin, have useful roles as emulsifiers. Mono-and diglycerides contribute to shortening performance and act as staling inhibitors in bakery produces. Lecithin is used as a mold release agent in confections, to control fat bloom in chocolate candied, and as an antispattering agent in cooking margarines.

  Fats and oils are available in variety of forms. Butter, cooking oils margarines, salad oils, and shortenings are essentially all-lipid forms. Salad dressings and mayonnaise are composed of high proportions of fats or oils. Ingested and mayonnaise are composed of high proportions of fats or oils. Ingested fats and oils include not only those from obvious source but also those from invisible fat sources, such as cereals, cheese eggs, fish, fruits, legumes, meat, milk nuts and vegetables. This latter group constitutes approximately 60% of the dietary fat.

  Salad and cooking oils are prepared from cottonseed oil, soybean oil. Corn oil peanut oil, safflower oil, olive m, or sunflower seed oil. These oils are usually refined, bleached, and deodorized. Some oils may be lightly hydrogenated to provide special properties and to enhance flavor stability.

  Margarines, used mostly as table spreads and to some extent as cooking fats, are prepared by blending suitably prepared fats and oils with other ingredients, such as milk skids, salt, flavoring materials, and vitamins a and d. The fat content must be at least 80%. Vegetable oils are used predominantly for manufacture of marine although some animal fats are used. The fats may be single hydrogenated fats, mixtures of hydrogenated fats, or blends of hydrogenated fats and unhydrogenated oil. Special margarines are prepared in response to medical research, which implies a possible superiority for these types of margarines, especially for persons prone to atherosclerotic conditions.

  Commercial shortenings are semisolid plastic fats made with or without emulsifiers. Plasticity, or ability to be worked, is a major feature distinguishing these from other fats. Original shortenings consisted of lard or tallow, but hydrogenated vegetable oils and various combinations of fats are used to build in specific properties desired for baking. Cottonseed oil, soybean oil tallow and lard are the principal fats used in shortenings, however, no natural fat possesses all of the desired characteristics.

  Butter, obtained by churning cream, is a water-in–oil emulsion containing 80-81% milk fat, which is present in plastic form. Other constituents in small amounts include casein, lactose, phosphatides, cholesterol, calcium salts, and usually 1-3% sodium chloride. Varying but small amount of vitamin a, e, and d also are present, along with flavor bodies consisting of diacetyl, lactones, and butyric and lactic acids.

  Cocoa butter, derived from the cocoa bean, is a fat preferred for confectionary uses it is usually in insufficient supply and is costly, so that many efforts have been made to substitute for it or to find suitable extenders.

                  Nomenclature of lipids in foods

    The nomenclature of lipids includes a broad range of terms because trivial manes are used in commerce, because systematic names.

A nomenclature suitable for describing the stereochemistry of glycerol derivatives has been proposed by the IUPAC-IUB commission on biochemical in which the secondary hydroxyl is shown to the left and the top carbon is c-1 the term “sn”(stereo specifically numbered) differentiates this numbering system from conventional systems that convey no steric information. This term is inserted immediately preceding the term signifying glycerol, and is separated from it by a hyphen.

  Triglycerides are named as derivatives of glycerol and the exact placement of substituents can be indicated in accord with the sn system. Thus a triglyceride containing palmitic (C-1), oleic (C-2), and stearic acids (C-3) is named sn-glyceryl-1-palmitate-2-oleate-3-steareate, frequently, the glyceryl term omitted and the same triglyceride is known as palmito-oleo –stearin. A diacid triglyceride containing two molecules of palmitic acid and one of stearic acid could be named dipalmitostearin or steartodipalmtin.

  The phospholipids most import in food is those containing a molecule of phosphoric acid etherified at one position of the glycerol molecule. The phosphoric acid in turn is esterified to another moiety, such as choline, ethanolamine, or inositol. Nomenclature of the phosphoglycerides is similar to that of triglycerides. Thus, the substance know in commercial as “lecithin” is designated 1,2-diacyl-sn-glycero-3-phosphory” is used for the portion of the molecule exclusive of choline. Similar designations apply to phosphatidylethanolamine, phosphatidylinositol, and others.

      The fatty acids in lipids are usually aliphatic compounds which may be saturated or unsaturated and, in limited cases, may have branched chains. Nomenclature of the fatty acids requires both a systematic approach and knowledge of trivial names that are frequently encountered.

  According to a system adopted at the Geneva Convention, fatty acids are named in accord with the parent hydrocarbon. The final “e” in the name of a hydrocarbon is replaced by “-oic” when referring to the saturated acid. Thus hexadecanoic acid (commonly know as palmtic acid) is related to the 16c hydrocarbon, hexadecane. The suffix “-ene” is used in naming hydrocarbons containing double bonds. Accordingly, the 16-carbon acid with one double bond is hexadecenoic acid and has the trivial name palmitoleic acid. Fatty acids with more than one double bond in the molecule have the suffix”-dienoic”, “-trienoic,” or other suitable designations for the number of double bonds.

第三課  脂類化合物及其在食品中的用途

食shi用yong脂zhi類lei的de組zu成cheng和he化hua學xue性xing質zhi是shi複fu雜za的de
，因yin為wei食shi用yong脂zhi類lei包bao括kuo了le多duo種zhong類lei型xing的de化hua合he物wu
，這zhe些xie化hua合he物wu受shou到dao了le與yu食shi物wu中zhong其qi它ta成cheng份fen的de多duo種zhong相xiang互hu作zuo用yong。單dan離li類lei脂zhi中zhong所suo發fa生sheng的de重zhong要yao而er確que定ding的de化hua學xue反fan應ying可ke能neng會hui由you於yu某mou些xie因yin素su而er使shi之zhi改gai變bian，例li如ru該gai類lei脂zhi在zai細xi胞bao組zu織zhi體ti係xi中zhong所suo處chu的de位wei置zhi，水shui分fen的de存cun在zai或huo不bu存cun在zai，類lei脂zhi經jing受shou過guo度du熱re或huo輻fu射she方fang麵mian的de處chu理li。金jin屬shu，不bu論lun象xiang離li子zi那na樣yang呈cheng遊you離li態tai的de，還hai是shi作zuo為wei有you機ji金jin屬shu化hua合he物wu結jie構gou成cheng分fen的de
，都dou會hui影ying響xiang脂zhi類lei的de化hua學xue行xing為wei

，尤you其qi是shi氧yang化hua作zuo用yong。食shi物wu的de非fei脂zhi成cheng分fen也ye可ke能neng與yu脂zhi類lei互hu相xiang作zuo用yong，導dao致zhi食shi品pin品pin質zhi的de變bian化hua。

脂類化合物的定義和分類

    食品消費者和食品加工者利用了來自稱為“油脂”的營養素族中的多種物質。油脂是一係列稱為脂類化合物中的最普遍的一類。“脂類”一詞在未刪略的韋氏詞典中的定義是“任何一族通常溶於乙醚、氯仿和其它油脂溶劑而僅微容與水且與蛋白質
、碳水化合物一起構成活細胞重要結構成分的物質及其有關的衍生化合物，有時還包括類固醇和類胡蘿卜素。”這一定義描述了很廣的一大類具有某些共同性質和某些共同結構的物質。

    布盧爾提出的脂類分類法包括的以下便於區分許多脂類物質的主要方麵：

    1.簡單脂類（中間脂類）——脂肪酸和醇類形成的脂。

    a.油脂：脂肪酸和甘油形成的脂。

    b.蠟：脂肪酸與非甘油的其它醇類所形成的脂。

    2.複合脂類——除脂肪酸與醇形成的脂外，還含有其它基團的化合物。

    a.磷脂：含有脂肪酸
、磷酸和通常含氮的其它基團的脂。

    b.腦苷脂：含有若幹個脂肪酸
、一個碳水化合物和一個含氮部分，但不含磷酸的化合物。

    c.其它複合脂：神經鞘類脂和腦硫脂。

    3.衍生脂類——由中性脂類或複合脂類衍生出來具有脂類一般性質的物質。

    a.脂肪酸。

    b.醇類：通常為直鏈高級醇和固醇。

    c.烴類。

    食物中可能含有任何一種或全部上述的脂類物質
，但最主要的是油脂（即甘油脂）和磷脂。“油脂”一詞適用一切甘油三酸脂，而不論它們在常溫下是固態或液態。液態油脂通常稱為油類。豆油、棉籽油、橄欖油等都是來自植物的油。豬油和牛、羊脂是典型來自動物的固態油脂。不過，來源於馬的油脂在室溫下是液態的，故稱之為馬油。

    油脂也可以根據它們的屬性來分類。五個公認的油脂族為：乳脂屬、月桂酸屬
、油酸-亞油酸屬、亞麻酸屬、動物儲藏脂肪屬。

    乳脂屬主要由反芻動物乳汁中的油脂構成
，尤以乳牛乳為多
，不過在某些地區，可能以水牛
、綿羊和山羊乳為多。乳脂的特征是含有30～40%油酸、25～32%棕櫚酸和10～15%硬脂酸。一般還含有相當多的C4～C12酸，而且是唯一含有丁酸的常用油脂
，丁酸含量因油脂來源不同而異，範圍約在3～15%之間。乳脂組成特別容易因動物食料所引起的變化而受到影響。

    月桂酸屬油脂的特征是含有高比例（40～50%）的月桂酸（C12）和C8、C10
、C14、C16和C18酸(suan)。它(ta)的(de)不(bu)飽(bao)和(he)酸(suan)的(de)含(han)量(liang)非(fei)常(chang)低(di)，這(zhe)是(shi)它(ta)貯(zhu)藏(zang)限(xian)期(qi)很(hen)常(chang)的(de)原(yuan)因(yin)。由(you)於(yu)這(zhe)類(lei)油(you)脂(zhi)的(de)碳(tan)鏈(lian)短(duan)，所(suo)以(yi)其(qi)熔(rong)點(dian)往(wang)往(wang)較(jiao)低(di)。應(ying)用(yong)最(zui)廣(guang)泛(fan)的(de)這(zhe)一(yi)類(lei)油(you)脂(zhi)來(lai)源(yuan)於(yu)椰(ye)子(zi)
、油棕子和巴巴蘇棕櫚果。

    油酸-亞麻酸屬油脂是數量豐富、品種最多、僅來源植物的油脂。這些油脂含飽和脂肪酸通常低於20%，且以油酸和亞油酸為主。這類油脂一般從棉籽、玉米胚芽
、芝麻、花生米
、葵花籽、紅花籽以及橄欖和油棕的種皮（即果肉）中取得的。

    亞麻酸屬油脂中含有大量亞麻酸，不過也可能含有較多的油酸和亞油酸。此屬中最主要的食用油是大豆油其它還有麥胚油、大麻籽油、紫蘇子油、亞麻子油等。亞麻酸含量最高是產生幹性油特性的原因
，尤其是亞麻酸含量高達50%的亞麻子油。

動物脂肪屬主要由豬油、牛脂和羊脂組成。它們以含30～40%的C16和C18飽和脂肪酸和高達60%的油脂
、亞油酸為特征動物脂肪的熔點比較高，部分原因是它們的飽和脂肪酸含量和甘油脂類型所致。就後一點而論，飽和脂肪酸含量高達60%的植物種子油脂中通常幾乎不含三飽和脂肪酸甘油脂，而飽和脂肪酸含量為55%的牛羊脂，卻含有高達26%的甘油飽和三酸脂。甘油三酸脂組成上的不同影響到油脂的物理性質，進而對所給油脂的使用方法產生很大的影響。

脂類在食物中的作用和用途

    油脂是最集中的食物能量源。每克油脂可提供9kal熱(re)量(liang)，這(zhe)約(yue)為(wei)同(tong)量(liang)蛋(dan)白(bai)質(zhi)或(huo)碳(tan)水(shui)化(hua)合(he)物(wu)提(ti)供(gong)熱(re)能(neng)的(de)一(yi)倍(bei)。油(you)脂(zhi)是(shi)脂(zhi)溶(rong)性(xing)維(wei)生(sheng)素(su)的(de)載(zai)體(ti)，它(ta)賦(fu)予(yu)食(shi)物(wu)以(yi)風(feng)味(wei)和(he)可(ke)口(kou)性(xing)
，並(bing)給(gei)人(ren)飯(fan)後(hou)以(yi)飽(bao)感(gan)。

    以甘油三酸脂、磷脂、膽固醇和膽固醇脂形式存在的脂類對生物膜和細胞壁的結構、組成和滲透性起著重要的作用。它們還有在植物果實、種(zhong)子(zi)中(zhong)和(he)動(dong)物(wu)體(ti)內(nei)貯(zhu)藏(zang)能(neng)量(liang)的(de)效(xiao)用(yong)。脂(zhi)類(lei)是(shi)脂(zhi)肪(fang)組(zu)織(zhi)的(de)主(zhu)要(yao)成(cheng)分(fen)。脂(zhi)肪(fang)組(zu)織(zhi)是(shi)機(ji)體(ti)的(de)保(bao)溫(wen)層(ceng)，對(dui)內(nei)髒(zang)器(qi)官(guan)油(you)防(fang)震(zhen)作(zuo)用(yong)，是(shi)機(ji)體(ti)體(ti)形(xing)的(de)構(gou)建(jian)物(wu)。

    油脂作為炸用脂或冷卻用油使用時，它起著可控的熱交換介質的作用，同時也油色、香

、味的貢獻。作為起酥油
，它通過潤滑作用和某種能力（改變其它組分見的相互作用）dejiehefuyubeikaoshipinyishusongrouruandepinzhi。zuoweiselayou，tadefengweiwuzhidezaiti
，fuyushiwuyikougan
，dangyuqitazufenyiqiruhuaxingchengzhanxingkedaochudetiaoweipinhuoduozhibangutaidesuoweidanhuangjianghuosepin。tangguozhongchangyongzhuanmentiaoxuanhuozhizuodeyouzhi，tebieshituceng、塗膜劑使用。這類專用脂肪必須在溫度為體溫附近時有狹窄融化區。

    其它脂類物質，如甘油單酸酯和甘油二酸酯以及某些磷脂（如卵磷脂）
，yongzuoruhuajiyouhenhaodexiaoguo。ganyoudansuanheganyouersuanzaibeikaozhipinzhongfuyuzhipinyisongcuidexingneng，bingqizhekanglaohuajidezuoyong。luanlinzhikeyiyongzhetangguodetuomoji
，keyonglaikongzhiqiaokelituyitangguodebiaomianchuyoufanshuang，yekezuorenzaonaiyoujiareshidefangjianjishiyong。

    我們可以獲得多種形式的油脂。奶油、烹飪油、人造奶油、selayouheqisuyoujibenshangshiquanzhidexingshi。selatiaoweipinhedanhuangjiangshiyougaobilideyouzhigouchengde。womensherudeyouzhibujinbaokuomingxiandeyouzhiziyuan
，yebaokuolaizinaxiebuxianyandeyouzhiziyuan
，rugulei、幹酪、蛋黃、魚類、水果類、豆類、肉類
、乳類

、堅果類、蔬菜類等等。後一組約占攝入油脂重量的60%左右。

    色拉油和烹飪油由棉籽油、大豆油
、玉米油
、花生油、紅花油、橄欖油或葵花籽油製成。這些油通常要經精煉
、脫色、脫臭處理。有些油經輕度氫化處理可獲得特殊的性質，並且增強風味的穩定性。

    人造奶油主要用作餐用塗抹油，也有一定數量用作烹飪油.人造奶油由精製的油脂和其他配料如乳固體

、鹽香料和維生素A、D等經適當調配而製成。起脂肪含量至少要有80%。製zhi造zao人ren造zao奶nai油you主zhu要yao是shi用yong植zhi物wu油you，不bu過guo也ye用yong一yi點dian動dong物wu脂zhi肪fang。製zhi造zao人ren造zao奶nai油you的de油you脂zhi可ke以yi是shi單dan一yi的de氫qing化hua脂zhi或huo氫qing化hua脂zhi的de混hun合he物wu
，也ye可ke以yi是shi氫qing化hua脂zhi和he未wei氫qing化hua油you的de混hun合he物wu。增zeng加jia多duo不bu飽bao和he脂zhi的de用yong量liang可ke製zhi成cheng專zhuan用yong的de人ren造zao奶nai油you。這zhe類lei專zhuan用yong的de人ren造zao奶nai油you已yi經jing根gen據ju醫yi學xue研yan究jiu的de要yao求qiu生sheng產chan出chu來lai了le。醫yi學xue研yan究jiu表biao明ming
，這zhe種zhong特te殊shu形xing式shi的de人ren造zao奶nai油you可ke能neng有you好hao處chu，尤you其qi對dui於yu動dong脈mai粥zhou樣yang硬ying化hua病bing傾qing向xiang的de人ren更geng有you益yi。

    商品起酥油是半固體的可塑性脂肪

，製造時可加乳化劑或不加乳化劑。可塑性（即經受壓練的性能）是shi商shang品pin起qi酥su油you區qu別bie與yu其qi他ta油you脂zhi的de主zhu要yao特te征zheng。早zao先xian起qi酥su油you的de成cheng份fen是shi豬zhu油you或huo牛niu羊yang脂zhi，而er現xian在zai則ze用yong各ge種zhong植zhi物wu油you和he各ge種zhong混hun合he油you脂zhi
，以yi形xing成cheng烘hong烤kao所suo要yao求qiu的de特te殊shu性xing質zhi。棉mian籽zi油you、大豆油、豬油、牛羊脂是用作起酥油的主要油脂。可是
，沒有哪種天然的油脂具備所有我們所要求的特性。

    奶油經稀奶油經攪製得到，是一種含80～81%乳糖（以可塑狀態出現）的油包水型乳膠。奶油中其它成分的數量都較少，包括酪蛋白
、乳糖、磷脂、膽固醇和鈣鹽
，通常還有1～3%的氯化鈉。奶油中含量少而不定的維生素A
、E和D
，此外還有由丁二酮、內酯、丁酸和乳酸組成的風味物質。

從cong可ke可ke豆dou來lai的de可ke可ke脂zhi是shi糖tang果guo製zhi造zao業ye上shang比bi較jiao適shi用yong的de脂zhi肪fang。但dan可ke可ke脂zhi常chang常chang供gong不bu應ying求qiu

，而er且qie價jia格ge昂ang貴gui，因yin此ci人ren們men為wei尋xun找zhao合he適shi的de增zeng補bu料liao以yi替ti代dai可ke可ke脂zhi作zuo出chu了le許xu多duo的de努nu力li。

食用脂類的命名法

    脂類命名法中包括來的術語範圍較廣，這是由於商業上使用的是俗名
、科技文獻中使用的是係統命名法，而為了表示一些帶有複雜科學名稱的物質又用合適的速記名稱的緣故。

    國際純粹化學和應用化學聯合會-國際生物化學聯合會（IUPAC-IUB）的(de)生(sheng)物(wu)化(hua)學(xue)命(ming)名(ming)法(fa)委(wei)員(yuan)會(hui)已(yi)經(jing)提(ti)出(chu)了(le)一(yi)種(zhong)適(shi)合(he)於(yu)描(miao)述(shu)甘(gan)油(you)衍(yan)生(sheng)物(wu)立(li)體(ti)化(hua)學(xue)的(de)命(ming)名(ming)法(fa)。這(zhe)一(yi)命(ming)名(ming)法(fa)采(cai)取(qu)了(le)費(fei)舍(she)爾(er)垂(chui)直(zhi)碳(tan)鏈(lian)投(tou)影(ying)法(fa)


，在(zai)垂(chui)直(zhi)碳(tan)鏈(lian)上(shang)仲(zhong)碳(tan)羥(qiang)基(ji)列(lie)在(zai)左(zuo)邊(bian)
，頂(ding)端(duan)碳(tan)原(yuan)子(zi)即(ji)為(wei)C-1。縮寫術語為“sn”（按立體定向編號）將該編號係統與不反映立體信息的傳統命名係統區分開來。此速寫術語直接插在表示甘油之詞的前麵，並用連綴號與之分開。

    甘油三酸酯按甘油的衍生物命名
，其取代基的確定位置可按立體定向編號（sn）係統表出。這樣
，含有棕櫚酸（C-1）、油酸（C-2）和硬脂酸（C-3）的甘油三酸脂的命名便是：sn-甘油基-2-油酸酯-3-硬脂酸酯。通常略去甘油基一詞
，而稱該甘油三酸酯為棕櫚酰-油酰硬脂酰甘油酯。含有二分子棕櫚酸和一分子硬脂酸的二酸式甘油三酸脂可命名為二棕櫚酰硬脂酰甘油酯或硬脂酰二棕櫚酰甘油酯。

    食品中最重要的磷脂是那些含有一分子（在甘油分子上某一位置上酯化的）磷酸的磷脂。此磷酸本身又與另一部分如膽堿、乙醇胺或肌醇分子酯化結合。磷酸甘油酯的命名法和甘油三酸酯的命名法相同。譬如，商業上稱為“卵磷脂”的物質應寫成1
，2-二酰基-sn-甘油基-3-磷酸膽堿。卵磷脂是膽堿磷酸甘油酯，也稱為磷脂酰膽堿或最好稱為3-sn-磷脂酰膽堿。磷脂酰一詞用來表示除膽堿以外的那一部分卵磷脂分子。類似這樣的名稱有磷脂酰乙醇胺（腦磷脂）

、磷脂酰肌醇和其它物質。

    zhileizhongdezhifangsuantongchangshibaohedehuobubaohedezhizuhuahewu
，shaoshuqingkuangxiahaikenengyouzhilian。zhifangsuandemingmingxuyaoxitongmingmingfahechangyusumingliangfangmiandezhishi。

根據日內瓦會議所采納的係統，脂肪酸是按照它的母體烴來命名的。當提到飽和脂肪酸時，便將烴類名稱的最後字母“e”用“oic”代替。這樣
，hexadecanoic acid十六烷烴（通常稱為棕櫚酸）即是與16C的烴hexadecane（十六烷）相應的脂肪酸。後綴“ene”用來表示含雙鍵的烴類。據此，有一個雙鍵的16C酸即為hexadecanenoic acid十六稀酸
，俗名稱為棕櫚油酸。脂肪酸分子內有多於一個雙鍵時，其後綴為“-dienoic”（雙稀）、“-trienoic”（三稀）或其它恰當表示雙鍵數目的後綴。

Lesson 3  Lipids and Their Uses in Food

imposition n.①征稅;稅,稅款;負擔 ②增加,強迫接受,過分的要求 ③欺詐

stress  n. vt. ①壓力,重壓,緊迫,緊張 ②重要,重點,強調 ③應力

unabridged 未刪節的,未節略的,完整的

ether ①醚 ②乙醚

chloroform氯仿,三氯甲烷

sparing a.①節約的,吝惜的,愛惜的 ②貧乏的,少量的

fat ①脂肪,肥肉 ②多脂肪的,肥的

carotenoid 類胡蘿卜素,類葉紅素

alcohol ①醇,醇元 ②乙醇,酒精

glycerol甘油,丙三醇

phospholipid磷脂

cerebrosides腦苷酯類          cerebellum小腦

sphingolipid (神經)鞘類脂物     sphingomyelin (神經)鞘髓磷脂

sulfolipid 硫脂

glyceride甘油酯

ambient a.周圍的,包圍著的

lard ①熟豬油 ②用肥肉餡填滿 ③脂肪的

tallow  (煉製牛,羊)油脂     tallow oil  (動物)脂油

tallowy 脂肪的,油脂的,油哈味,哈敗的(指油脂)

lauric acid 月桂酸,十二(烷)酸

oleic油酸的

oleic-linoleic acid 油酸-亞油酸

linoleic acid(=linolic acid) 亞油酸,十八(碳)二烯-[9,12]-酸,罌酸

linolein 亞油精,甘油三亞油酸酯

linolenic acid 亞麻酸,十八(碳)三烯-[9,12,15]-酸

depot ①倉庫,堆棧 ②基地 ③[法]酒中沉澱  depot-fat儲存脂肪

buffalo水牛

palmitic acid 棕櫚酸,十六(烷)酸,軟脂酸

stearic acid硬脂酸,十八(碳)(烷)酸

butyric ①丁酸的,酪酸的 ②丁酸(發酵)菌

coconut 椰子           coco 椰子樹,椰子

babassu nut  (巴西)巴巴蘇棕櫚(堅)果

coquilla nut棕櫚果

sesame芝麻

sunflower向日葵

safflower紅花

pulp ①漿,果漿 ②打漿

germ n.①微生物,細菌,病菌 ②[生]幼芽,胚原基 ③萌牙,起源 vi.(喻)萌芽,發生

hempseed oil大麻籽油

perilla oil紫蘇子油

linseed oil亞麻子油

bovine牛,牛的

ovine綿羊的,似綿羊的

palatability 可口性,味道,味道質量   ～ test口味質量評定

palatable ①可口的,味美的,好吃的.②[喻]愜意的,合趣味的

satiety n.飽足,過飽,厭膩   satiete vt.使充分滿足,使飽享,使過飽生厭,使厭膩

triglyceride甘油三酸酯

cholesterol膽甾醇,膽固醇

permeability滲透性,穿透性

adipose a.脂肪質的,脂肪多的
，肥胖的   n.動物脂肪,脂細胞,脂肪

fry ①油炸食品 ②油炸,油煎,油炒 ③魚苗,小魚

shortening ①起酥油 ②油酥 ③縮短     shorten油酥麵團

impart vt.①把…分給,給予,傳遞 ②告訴,透露

emulsify 乳化

viscous粘的,有粘性的,粘滯的

pourable dressing可倒出的調味品

dressing ①(畜,禽,魚)剝皮(或去毛
、鱗),去內髒及分割加工  ②烤禽前腹內填餡 ③(麵粉)

        過篩 ④加上調味品(液),佐料 ⑤修整,包裝

margarine 人造奶油

mayonnaise ①蛋黃醬 ②蛋黃醬拌的涼菜

enrobe (糖果冰淇淋等)浸掛巧克力漿或其他塗漿.

melting ①溶化,熔煉,煉出(脂油).②溶解,融化.③細致的,軟的,柔和的,淡的(口味,風味)

short ①短的.②酥的,鬆脆的.③(飲料等)濃的,強的④[複]次貨,次粉,細糠,二級麥皮

diglyceride 甘油二酸酯

lecithin 卵磷脂

stale幹硬的,不新鮮的,發黴的,走了氣的,走味的(煙,酒等),陳腐的

spatter vt.①濺,濺汙,灑 ②汙蔑,中傷  vi.滴下,飛濺  n.①濺,灑,滴落,飛濺 ②(雨等的)

      淅瀝聲,飛濺聲 ③潑濺的汙跡④少量,點滴

antispatter 防濺

antispattering agent 防濺劑

cereal ①禾穀類,五穀,糧穀,穀物的,穀類作物的,穀類製成的.②穀類食物.

      ③穀物製的食品 ④肉餡中麵粉或米粉的加料

bleach 漂白劑,漂白度,脫色

deodorize vt.除去…臭味,防止…的臭味  deodorizer 除臭劑,解臭劑,防臭劑

hydrogenated fat 氫化脂,硬化油   hydrogenate 氫化,還原

atherosclerotic 動脈粥樣硬化的   atherosclerosis 動脈粥樣硬化

emulsifier ①乳化劑 ②乳化器

emulsion ①乳濁液,乳膠,乳劑 ②香腸的細斬拌肉餡

churning ①奶油攪拌,攪乳 ②一次生產奶油的批量,一次提製的奶油

cream ①稀奶油,(鮮)奶油,②稀奶油做的,③乳漿,④利口酒

casein酪蛋白,幹酪素

diacetyl 雙乙酰,丁二酮

lactone 內酯

extender 補充劑,增補劑

shorthand速記

stereochemistry 立體化學

vertical 垂直的

precede vt. ①先於…,位於…之前;比…優先,(地位等)高於… ②在…前加上,為…加上引

       言. Vi.在前麵,居前,領先

signify vt.①表示,表明,意味 ②預示    vi.①要緊,有重要性 ②[美俚]冒充內行

hyphen n. 連字號(即-)  vt.用連字號連接

palmito-oleo-stearin 棕櫚酰-油酰-硬脂酰(甘油酯)

palmitate 棕櫚酸酯

dipalmitostearin 二棕櫚酰硬脂酰(甘油酯)

stearodipalmitin硬脂酰二棕櫚酰(甘油酯)

choline 膽堿

ethanolamine 乙醇胺;氨基乙醇

inositol 肌醇,環己六醇

phosphatidyl 磷脂酰

aliphatic 脂肪族的，屬於開鏈碳化合物

hexadecanoic acid 十六(烷)酸   ( =palmitic acid)

hexadecane 十六烷

hexadecenoic acid 十六烯酸

palmitoleic acid 棕櫚油酸

convention n. ①(政治,宗教,政黨等的)會議,大會,全國性大會.②召集,集會,③`公約,協定

            ④慣例,習俗,常規.

Presence or absence

Existence and inexistence

F: many important and well-understood chemical changes that occur in an isolated lipid may be modified by such factors as location of the lipid in a tissue system, the presence or absence of water, and the imposition of such stresses as heat or radiation.

 In turn      : 

   依此地 ( 兩者常用於
，實驗試劑加 入、作用方式。

 Respectively  :各自地

F： Differences in triglyceride composition affect physical properties, and this Differences in triglyceride composition affect physical properties, and this in turn greatly influences the use to which a given fat is put.

F： The simple sugars (monosaccharides0 are basically aliphatic polyhydroxy aldehydes and ketones: HOCH2- (CHOH) n-CHO and HOCH2- (CHOOH) n-1-C-O-Ch2OH, called “aldoses” and “ketoses,” respectively.

Concentrate :  富集

Condense in:   濃集於

F:  Fats and oils the most concentrated source or food energy.

F:  D-glucose and D-fructose, are condensing in such a way that their reactive functions are lost to form the disaccharide no reducing sugar, sucrose.

代替

Substitute for :

  Instead  of : 

Replace   :

F:  Cocoa butter, derived from the cocoa bean, is a fat preferred for confectionary uses it is usually in insufficient supply and is costly, so that many efforts have been made to substitute for it or to find suitable extenders.

F: The final “e” in the name of a hydrocarbon is replaced by “-oic

  English  experience

SOME GOOD SENTENCES：

1.  linseed oil contains up to 50% linolenic acid.  (up to 意為達到）

2.        They perform a function of energy storage in seeds, fruits of plants and animals.(起…的功能)                                                   

3.        This definition describes a broad group of substances that have some properties in common and have some compositional similarities. (group 作名詞時，常作“基團、族”解)

4.        What we eat as well as how much we eat determine our nutrition status to an important extent, and influenced by a diversity of external and internal factors.( 很大程度上)

   Margarines, used mostly as table spreads and to some extent as cooking fats, are prepared by blending suitably prepared fats and oils with other ingredients.(某種程度上)

     本句中，define…as意為“給……下定義”或“將……定義為”。That in general are soluble in ether… in water 是定語從句，修飾a group of substances; that with proteins and carbohydrates constitute the principal structural components of living cells也是定語從句
，也修飾a group of substances。作為as的賓語
，any of a group of substances, related and derived compounds, steroids and carotenoids三者是並列的。

         fats and oil 為主句主語


， as frying fats or cooling oils的as短語做主語的補語
， where引導的狀語從句修飾謂語are used,此從句中有兩個並列的不定式動詞 to provide as 和to contribute.

        as shortenings 為目的的狀語，主語they 指上文中的fats and oils, through 帶出的介詞短語（至句末）修飾謂語important 的方式狀語。Lubrication 和ability為介詞of 的並列賓語
，構成的介詞短語修飾a combination; To alter…other constituents 為不定式短語
，作an ability 的定語； among other constituents 是介詞短語，作定語
，修飾interaction.